Laboratory Sink Disposal Fact Sheet

MWRA Regulations for Sewer Discharge

Developed by ECOS (Environmental Compliance and Occupational Safety)

Key Takeaways

  1. All laboratory sinks and drains are connected to monitored pH neutralization systems.
  2. The MWRA regulates these neutralization systems and determines which substances are prohibited from being discharged.
  3. Laboratories must comply with MWRA regulations and ensure wastewater does not contain hazardous substances, flammable liquids, or infectious waste.
  4. Laboratories must consult ECOS before potentially discharging polluted wastewater.

Purpose

The guidance is to provide laboratories on Northeastern University’s Boston Campus (the University) with the regulations governing the disposal of materials into the Massachusetts Water Resource Authority (MWRA) sewer system.

 

Background

The University maintains 10 industrial wastewater treatment systems (IWPS) for the neutralization of laboratory wastewaters. Laboratory wastewater enters the IWPS for treatment prior to entering the main sanitary line, which feeds into the MWRA treatment system on Deer Island. The IWPS’s are installed in most academic and research buildings – Egan, ISEC, EXP, Hurtig, Mugar, Behrakis, 140 The Fenway, and Snell Engineering. Some academic buildings with lower daily flows are equipped with lime chip neutralization tanks instead of the larger pH neutralization systems.

The MWRA determines which materials are allowed for discharge and at what concentration. The MWRA enforces their regulations by periodically sampling the laboratory wastewater and issuing notices of violations and monetary fines should the University discharge any regulated pollutant over the permitted concentration. The MWRA lists which pollutants are not allowed for discharge in 360 CMR 10.000. Any material that poses a risk to the wastewater treatment process, its equipment, or to the personnel operating the equipment is strictly prohibited.

The discharge of treated laboratory wastewater is permitted at the University under two separate MWRA discharge permits held by the ECOS Department. Comprehensive sampling is required under these permits by the MWRA for all 10 wastewater treatment systems on campus. Continuous pH, flow, and temperature monitoring is also required for all 10 systems, in addition to daily inspections by certified wastewater treatment operators, and monthly preventative maintenance inspections to ensure all equipment and systems are in working order. Any new or modified wastewater discharges must be reviewed by the ECOS department prior to entering the laboratory drains. Please reach out to ECOS prior to discharging any potentially polluted wastewater into the laboratory drains.

 

Environmental Compliance Requirements

The University’s MWRA discharge permits do not allow hazardous materials into the sewer system. Prohibited materials include those listed in 360 CMR 10.000 and within the University’s MWRA wastewater permits. Should you require disposal of any of these prohibited materials, contact ECOS or OARS for guidance.

01. Specific Prohibited Materials

    1. Groundwater, storm water, surface water, or roof water.
    2. Non‐Contact Cooling Water, except when permitted by the MWRA.
    3. Fuel oil, crude oil, lubricating oils, grease, hydrocarbons, waxes, and fats.
    4. Any liquid, solid, or gas including, but not limited to, gasoline, kerosene, naphtha, benzene, toluene, xylene, ethers, alcohols, ketones, aldehydes, peroxides and methyl ethyl ketone, which may be sufficient, either alone or by interaction with other substances, to create a fire or explosion hazard.
        • Includes wastewaters with a closed cup flash point of less than 140⁰F.
        • Includes any pollutant with an exceedance of 10% of the lower explosion
    5. Any noxious or malodorous liquid, gas, or solid which could contribute to the creation of a public nuisance or make it dangerous for personnel or equipment to enter the sewer for purposes of maintenance and repair.
    6. Any wastewater with a pH lower than 5.5 or higher than 12.0 or with any corrosive or injurious property which may cause damage or be hazardous to the sewer system or personnel.
    7. Any material that prohibits or obstructs the flow within the sewer system, such as sand, mud, metal, glass, wood, plastics, improperly shredded garbage, rubber, latex, lime or other slurries, grease, animal guts or tissues, bones, hair, hides or fleshings, entrails, feathers, ashes, cinders, stone or marble dust, straw, shavings, grass clippings, rags, spent grains, spent hops, tar, asphalt residues, residues from refining or processing fuel or lubrication oil, or glass grinding or polishing Wastes.
    8. Any wastewater with a temperature above 180⁰F.
    9. Any radioactive materials.
    10. Any hazardous waste.
    11. Any infectious or physically dangerous medical or biological waste.
    12. Any oxygen‐demanding pollutants (BOD, COD) that would interfere with treatment at the MWRA.

02. Permit Specific Prohibited Materials

Prohibited Materials Maximum Concentration (mg/L)
1,1‐Dichloroethylene 0.3
Acrolein 0.15
Antimony (total) 10.0
Arsenic (total) 0.5
Benzene 0.3
Cadmium (total) 0.1
Chromium (hexavalent, +6) 0.5
Chromium (total) 1.0
Copper (total) 1.0
Cyanide (total) 0.5
Formaldehyde 9.0
Hexachlorobutadiene Prohibited
Lead (total) 0.2
Mercury 0.001
Nickel (total) 1.0
Pesticides Prohibited
Phenol 5.0
Polychlorinated Biphenyls (PCBs) Prohibited
Selenium (total) 5.0
Silver (total) 2.0
Toxic Organics, Each 1.0
Toxic Organics, Total 5.0
Vinyl Chloride (Chloroethylene) 0.02
Vinylidene Chloride 0.3
Zinc (total) 1.0
Oil and grease 300

03. Any Toxic Organic Listed Below.

Each toxic organic has a permit limit of 1.0 mg/L. The total concentration of all detected toxics has a permit limit of 5.0 mg/L.

CAS No: Chemical Name
107‐13‐1 Acrylonitrile
75‐25‐2 Bromoform
75‐27‐4 Bromodichloromethane
74‐83‐9 Bromomethane
75‐15‐0 Carbon Disulfide
56‐23‐5 Carbon Tetrachloride
108‐90‐7 Chlorobenzene
75‐00‐3 Chloroethane
110‐75‐8 2‐Chloroethyl Vinyl Ether (mixed)
67‐66‐3 Chloroform
74‐87‐3 Chloromethane
124‐48‐1 Dibromochloromethane
75‐34‐3 1,1 ‐Dichloroethane
107‐06‐2 1,2‐Dichloroethane
156‐60‐5 t‐1,2‐Dichloroethene
78‐87‐5 1,2‐Dichloropropane
10061‐01‐5 c‐1,3‐Dichloropropene
10061‐02‐6 t‐1,3‐Dichloropropene
75‐71‐8 Dichlorodifluoromethane
100‐41‐4 Ethylbenzene
75‐09‐2 Methylene Chloride
100‐42‐5 Styrene
79‐34‐5 1,1,2,2‐Tetrachloroethane
127‐18‐4 Tetrachloroethene
108‐88‐3 Toluene
71‐55‐6 1,1,1‐Trichloroethane
79‐00‐5 1,1,2‐Trichloroethane
79‐01‐6 Trichloroethylene
75‐69‐4 Trichlorofluoromethane
108‐05‐4 Vinyl Acetate
1330‐20‐7 Xylene (total)
83‐32‐9 Acenaphthene
208‐96‐8 Acenaphthylene
120‐12‐7 Anthracene
92‐87‐5 Benzidine
56‐55‐3 Benzo(A) Anthracene
205‐99‐2 Benzo(B) Fluoranthene
207‐08‐9 Benzo(K) Fluoranthene
191‐24‐2 Benzo(GHI) Perylene
50‐32‐8 Benzo(A) Pyrene
85‐68‐7 Benzyl Butyl Phthalate
111‐91‐1 Bis (2‐Chloroethoxy) Methane
111‐44‐4 Bis (2‐Chloroethyl) Ether
117‐81‐7 Bis (2‐Ethylhexyl) Phthalate
101‐55‐3 4‐Bromophenyl Phenyl Ether
106‐47‐8 4‐Chloroaniline
91‐58‐7 2‐Chloronaphthalene
95‐57‐8 2‐Chlorophenol
7005‐72‐3 4‐Chlorophenyl Phenyl Ether
218‐01‐9 Chrysene
53‐70‐3 Dibenzo (A,H) Anthracene
132‐64‐9 Dibenzo Furan
95‐50‐1 1,2‐Dichlorobenzene
541‐73‐1 1,3‐Dichlorobenzene
106‐46‐7 1,4‐Dichlorobenzene
91‐94‐1 3,3’‐Dichlorobenzidine
120‐83‐2 2,4‐Dichlorophenol
84‐66‐2 Diethyl Phthalate
105‐67‐9 2,4‐Dimethylphenol
131‐11‐3 Dimethyl Phthalate
84‐74‐2 Di‐n‐butyl Phthalate
51‐28‐5 2,4‐Dinitrophenol
534‐52‐1 2‐Methyl‐4,6‐Dinitrophenol
121‐14‐2 2,4‐Dinitrotoluene
606‐20‐2 2,6‐Dinitrotoluene
117‐84‐0 Di‐n‐octyl Phthalate
122‐66‐7 1,2‐Diphenylhydrazine
206‐44‐0 Fluoranthene
86‐73‐7 Fluorene
118‐74‐1 Hexachlorobenzene
87‐68‐3 Hexachlorobutadiene
67‐72‐1 Hexachloroethane
193‐39‐5 Indeno (1,2,3‐cd) Pyrene
78‐59‐1 Isophorone
91‐57‐6 2‐Methylnaphthalene
95‐48‐7 2‐Methylphenol (o‐Cresol)
108‐39‐4 3‐Methylphenol (m‐Cresol)
106‐44‐5 4‐Methylphenol (p‐Cresol)
91‐20‐3 Naphthalene
98‐95‐3 Nitrobenzene
88‐75‐5 2‐Nitrophenol
62‐75‐9 N‐Nitrosodimethylamine
621‐64‐7 N‐Nitroso‐di‐n‐Propylamine
95‐95‐4 2,4,5‐Trichlorophenol
88‐06‐2 2,4,6‐Trichlorophenol
75‐07‐0 Acetaldehyde
107‐18‐6 Allyl alcohol
107‐05‐1 Allyl chloride
628‐63‐7 Amyl acetate
62‐53‐3 Aniline
100‐47‐0 Benzonitrile
100‐44‐7 Benzyl chloride
123‐86‐4 Butyl acetate
1395‐284‐6 Butylamine
4170‐30‐3 Crotonaldehyde
110‐82‐7 Cyclohexane
1194‐65‐6 Dichlorobenil
75‐99‐0 2,2‐Dichloropropionic acid
109‐89‐7 Diethyl amine
99‐65‐0 1,3‐Dinitrobenzene
124‐40‐3 Dimethyl amine
106‐89‐8 Epichlorohydrin
107‐15‐3 Ethylene diamine
106‐93‐4 Ethylene dibromide
98‐01‐1 Furfural
78‐79‐5 Isoprene
42504‐46‐1 Isopropanolamine dodecylbenzenesulfonate
115‐32‐2 Kelthane
2032‐65‐7 Mercaptodimethur
74‐93‐1 Methyl mercaptan
80‐62‐6 Methyl methacrylate
75‐04‐7 Monoethyl amine
74‐89‐5 Monomethyl amine
1338‐24‐5 Napthenic acid
1321‐12‐6 Nitrotoluene
75‐44‐5 Phosgene
75‐56‐9 Propylene oxide
108‐60‐1 2,2’‐Oxybis(1‐Chloropropane)
91‐22‐5 Quinoline
108‐46‐3 Resorcinol
27323‐41‐7 Triethanolamine dodecylbenzenesulfonate
121‐44‐8 Triethylamine
75‐50‐3 Trimethylamine
1300‐71‐6 Xylenol

Best Management Practices for Laboratory Sink Disposal

Laboratory sink disposal should be limited to handwashing and the final rinses of glassware. Chemical containers that previously held a regulated material should be rinsed three times with water (or acetone) with the rinseate being collected as a separate waste stream. After rinsing three times, remaining rinses with water can be disposed of down the drain.

Waste disposal should be determined prior to conducting any experiment. Review the ignitibility, corrosivity, reactivity, and toxicity of all generated waste streams. Waste streams exhibiting hazardous characteristics cannot be disposed of down the laboratory sink drain. Those characteristics include, but are not limited to, the following:

  1. Ignitability – flashpoints less than 140⁰F
  2. Corrosivity – pH less than 5.5 or greater than 12.
  3. Reactivity – such as organic peroxides, azide compounds, or other materials capable of explosion; sodium metals and anhydrides that react violently with water; and cyanides or sulfides that may emit toxic vapors when exposed to water.
  4. Toxicity – refer to regulated pollutants and toxic organic

Certain materials may be an allowable discharge to a laboratory sink drain. These materials may include certain cell growth buffers, salt solutions, deactivated biological samples, and dilute acid and caustic solutions. Please confirm disposal requirements with OARS and ECOS prior to generating the waste stream. Diluting of a waste stream to meet disposal requirements is prohibited.

ECOS is Here to Help

For any questions, please contact a member of the ECOS team at

ECOS@northeastern.edu